I make a tune on 91/93 pump gas and tune it to where the ignition is smooth and maybe shows active kr up to 1-2* under moderate load (i dont allow questionable detonation to exist under heavy load). Then i throw some VP MS109, VP110, or C16 whatever i have laying around. i do it with low fuel level of 91/93 of course so that when i add a small amount of the expensive stuff i end up with a higher octane rating. If you do this and the kr goes away then its real cylinder pressure based. If it stays and its always in the same load range then its likely a harmonic from the mechanical side.
i have also done it with E85 from a pump but i have to drive 2.5 hours to get to one of those pumps and shipping the fuel to my shop is lazy and is only 10 minutes from where i keep my cars. I would mix for a ratio around E20-30 (20-30% ethanol content) shouldnt throw the fueling off too bad and should raise the ignition kr threshold enough to separate true from mechanical knock.
the best way which i save for last is expensive but probably the best way and that is to invest in some knock ears.
https://www.haltech.com/product/ht-0...nock-ears-kit/
https://www.motorsportselectronics.c...nt=13654731524