Yes, that would be the proper way to do it, and yes the pins should be fine.
I am looking to do something similar, but instead of trying to find a place to install a high pressure switch I am just making a simple circuit that will show 4 volts to that pin on the PCM when the A/C is engaged. That will provide the same effect with out having to add a new port to the A/C system.
https://www.amazon.com/gp/product/B0...?ie=UTF8&psc=1
Is what I will be using to drop the voltage from 12V to 4V. For the source I was going to use Pin C2 39 for positive and Pin C2 43 for the ground, then for the positive output of 4V to Pin C2 14.
I haven't done it yet, so if anyone sees something wrong with this method feel free to speak up.